Journal of polymer science part a.
Bulk polymer pendant vinyl bonds.
The oh groups in pva also form strong hydrogen bonds.
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Poly vinyl alcohol pva is made by the hydrolysis of poly vinyl acetate pvac.
While pvms polymers have been known and synthesized for many decades limited in.
Poly methyl methacrylate pmma also known as acrylic or acrylic glass as well as by the trade names crylux plexiglas acrylic acrylite astariglas lucite perclax and perspex among several others is a transparent thermoplastic often used in sheet form as a lightweight or shatter resistant alternative to glass the same material can be used as a casting resin or in inks and coatings.
I have made resin pendants successfully and now i made a polymer clay pendant and tried to put resin on it and the resin is not sticking in spots.
Johannes karl fink in reactive polymers fundamentals and applications second edition 2013.
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Same thing happened again.
Gilliom reported the first study of the bulk catalytic hydrogenation of c c bonds of diene based polymers.
However the slow reaction rates were impractical and solvents were still used in the initial mixing of the polymer with the catalyst 3 10 liu and coworkers recently investigated bulk hydrogenation of diene based polymers via simple.
Regular polymers with small pendant groups crystallize more readily than do polymers with large bulky pendant groups.
Of the low molecular weight divinyl monomers egdma and dvb are the most effective cross linkers however pendant unreacted vinyl groups remain in the polymer architecture when egdma is used.
A siloxane polymer with pendant epoxide rings on the side chain of the polysiloxane polymer backbone when blended with diglycidyl bisphenol a ether and cured increases the mobility of the crosslinked network and the thermal stability.
Polymer chemistry 2008 46 18 6023 6034.
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Leading to the modiļ¬cation of pendant vinyl groups.
Therefore pvms represents a unique class of sens that offers the same functions as pdms with the additional ability to tune the chemical nature of the sen via vinyl based reactions.
Branched polystyrene with abundant pendant vinyl functional groups from asymmetric divinyl monomer.
Pva crystallizes more readily than pvac because of the bulky acetate groups in pvac.
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